Optical basicity

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August undefined, 2024

WebJun 25, 2024 · Basicity, polarizability, electronegativity and some physical constants are determined depending on experimental results. Also, the refractive index and optical band gap are calculated depending on the theoretical optical basicity and molar refractivity. WebAug 9, 2024 · The Figure S1b presents the optical basicity behavior for SixMg, SixCa, SixNNa, and SixNLiNa glasses in a higher magnification. The optical basicity is found for all silicate glasses to increase approximately linearly with total modifier content, while pyrophosphate glasses appear to partially deviate from this trend.

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WebThe optical basicity of complex nitrides can therefore be calculated by the same method established for oxides using the equivalent fractions and the basicity of the constituent … WebHello Kai Fauth, Slag Basicity is a measure of the acidic-basic character of the oxides, widely used by the glass scientists, slag metallurgists and some geologists as well. You will get … phillip painley do

Optical Basicity - Encyclopedia of Glass Science, Technology, …

WebThe study of polarizability, optical basicity, and electric susceptibility carried out on the new and very rare set of bismuth - tellurite glasses doped with Ho 3+ ions were fabricated by the conventional melt quenching process. The non-crystalline nature was confirmed by X-ray diffractometer measurements. Physical properties such as rare earth ... WebThe concept of optical basicities initially developed by Duffy for solid oxides was successfully transferred to low melting salts such as ionic liquids (ILs). Several ionic … WebApr 28, 2024 · The optical basicity follows the same trend as the electronic polarizability, which can be attributed to the more acidic nature of P 2 O 3 compared with TiO 2. Moreover, the decrease of the optical basicity with increasing TiO 2 content supports the low ability of TiO 2 compared with P 2 O 5 to transfer electrons to the surrounding cations. phillip painley md

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The influence of basicity on oxygen activity and antimony oxide f ...

For oxides, MO (M = Mg, Ca, Sr, Ba), the basicity moderating parameter of M gover… Arguments are presented justifying the use of fluoride optical basicity values (e.g… The optical basicity trend in alkali borate glasses has been studied in detail [2,13-… The basicity of the oxidic groups AlO 4 5−, SiO 4 4−, PO 4 3−, SO 4 2−, ClO 4 −, ca… The basicity of an oxide glass can be measured experimentally from the frequenc… WebMay 19, 2004 · The optical basicity treatment of oxidic network systems, for example silicates, has been successful in correlating a range of properties; since the method has the advantage of avoiding such problems as those associated with “single ion” activities, it allows comparisons between many different systems. However, several of the properties … try rebooting your pcWebThe physical, optical, and gamma ray shielding capabilities of the B 2 O 3-Bi 2 O 3-MoO 3 glass system have been evaluated. The optical basicity of the current samples rises from 0.781 to 0.897 with increasing Bi 2 O 3 concentration. The values of refractive index, dielectric constant and optical dielectric constant show uptrend and lies in the range of … phillip painter and muralist

"WebFeb 25, 2002 · The optical basicity for La 2 O 3 oxide is found to be 1.07, being much larger compared with typical glass-forming oxides such as B 2 O 3 (0.42) and SiO 2 (0.48) but being similar to heavy element oxides such as TeO 2 (0.93). " - Optical basicity

Optical basicity

A New Sulfide Capacity Model for CaO-Al - Wiley Online Library

WebMay 26, 2015 · A new sulfide capacity model for CaO-Al 2 O 3 -SiO 2 -MgO slags has been developed based on corrected optical basicity. The present model has taken charge compensation into consideration and postulated that Al exits in the form of [1/2Ca (AlO 4 )] 4– when NCaO is higher than NAl2O3 in slag. WebFeb 25, 2002 · The electronic polarizability and optical basicity of La 2 O 3 and related glasses have been determined from ultraviolet absorption spectra and calculations based …

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WebJun 25, 2024 · The optical basicity of the glass has been estimated and it has the values from 1.11 to 1.31 with varying vanadium content from zero to 5 mol%. Static dielectric … WebApr 8, 2024 · Physical properties were studied such as; X-ray diffraction, FTIR spectra, and UV–visible transmission. The optical basicity, average electro negativity have been estimated. The estimated...

WebThe optical basicity of the manufactured glass samples is increased from 0.577 to 0.862, which is a significant improvement. As the quantity of oxygen atoms in the produced glass samples diminishes, the oxygen packing density varies between 102.978 and 78.351, depending on the sample size. The energy of the optical band gap ranges between 3.878 ... WebAug 1, 2024 · Optical bandgap energy, refractive index, molar polarizability, molar electronic polarizability, electronic polarizability, and bandgap based oxide ion polarizabilities, optical basicity, electric susceptibility, and other important parameter were reported in this work.

WebFinding a parameter of the same type for solid oxides was not so easy. Modern theories of reactivity propose to consider the oxidizing power, acidity, basicity, and reducing power, as steps along a same continuum, instead of distinct phenomena [3]. Among parameters, Zhang’s scale of electronegativity [4], optical electronegativity and optical ... WebAug 13, 2002 · The acid−base properties of germanate glasses cannot presently be compared quantitatively with those of silicate, borate, and several other glasses because the optical basicity of the parent oxide, Λ(GeO2), has not yet been unequivocally established. The usual method of measuring optical basicity, relying on probe ions such as Tl+ or …

WebThis study explored a technical approach that can reduce the basicity of lignin-based biochar by utilizing FeCl 3 during production of ... USA). The concentration of As(V) was analyzed using an inductively coupled plasma/optical emission spectrometry (ICP/OES, Optima 5300 DV, PerkinElmer, USA). The reusability test was conducted in five ...

WebThe concept of optical basicity (Λ) is particularly suited to binary oxides and oxidic network materials such as silicates to characterize the acid–base nature of glasses and melts and to account for the complexation of metal cations by a variety of anionic frameworks. try redboostWebApr 15, 2007 · This relationship presents a general trend toward an increase in the oxide ion polarizability with increase in optical basicity. The Λ values estimated from α O 2-using Eq. (6) are given in Table 1 (columns 9–10). Large α O 2-(n) values over 2 Å 3 and large Λ values over 1.0 are obtained. That is, the rare earth oxides showing electronic polarizability … try red hairWebJun 7, 2024 · The main reason is that the optical basicity of transition metal oxides cannot be directly measured because the own d orbitals of cations are involved and because their metal-oxygen bonds have an... try rebooting your pc and then怎么弄WebIt is shown that optical basicity avoids the confusion that can arise from the use of empirical basicity ratios, particularly with regard to the effect of magnesia, and in addition, facilitates... phillip painter uhcWebDec 2, 2014 · Optical basicity depends on the electronegativity of the ions of an individual oxide. This feature represents the bonding characteristics, ionization ability, ion size, and consequently the mobility of free ions inside the slag. These properties affect the electrical conductivity of slags. try rebooting your pc and then launchWebDec 20, 2024 · Titanium-doped and titanium-free lithium borate glasses were prepared using a quenching method and high-purity-grade chemical substances. Structural analysis was carried out by Fourier transform infrared (FT-IR) spectroscopy and mechanical measurement. The states of the produced glasses were examined by x-ray diffraction, and … phillip painter born 1913WebOct 10, 2024 · Optical basicity is identified as the average electron donor power of a fluorinated or oxidic compound (Herrmann et al., 2015). For a glass system consisting of … phillippa lane emsworth